How to Layer Skincare Products Correctly

Master the art of skincare layering to maximise the benefits of every product in your routine.

You've curated a collection of quality skincare products, but are you applying them in the right order? Proper layering isn't just about preventing pilling or ensuring products absorb—it can significantly impact how well your products work. Get the order wrong, and you might be blocking active ingredients from reaching your skin or diluting potent serums before they can take effect.

The Golden Rule: Thinnest to Thickest

The fundamental principle of skincare layering is simple: apply products from thinnest to thickest consistency. Lightweight, water-based products go first because they can't penetrate through heavier, oil-based products. If you apply a rich cream before a watery serum, that serum sits on top of the cream barrier and can't reach your skin.

This rule has a scientific basis. Water-based products contain smaller molecules that can pass through the skin's lipid barrier more easily. Oil-based products create an occlusive layer that prevents evaporation but also prevents water-based ingredients from penetrating.

The Complete Layering Order: Morning Routine

Here's the optimal order for your morning skincare routine:

Step 1: Cleanser

Start with a gentle cleanser to remove overnight oil, sweat, and any residual products. For morning, a light gel or cream cleanser is usually sufficient—you don't need the same thorough cleansing as evening.

Step 2: Toner (Optional)

If you use a toner, apply it to damp skin immediately after cleansing. Toners can hydrate, balance pH, or deliver light doses of active ingredients depending on the formula. Skip this step if your toner is purely astringent—these are outdated and can be harsh on skin.

Step 3: Vitamin C Serum

Apply your Vitamin C serum to clean, slightly damp skin. Use 3-4 drops and gently pat onto face and neck. Vitamin C goes early in the routine because it's typically water-based and has a low pH that needs direct skin contact for optimal penetration.

Wait 1-2 minutes for your Vitamin C serum to absorb before moving to the next step. This allows the acidic formula to work without being neutralised by subsequent products.

Step 4: Other Water-Based Serums

If you use additional serums (like hyaluronic acid or niacinamide), apply them after Vitamin C. Apply from thinnest to thickest consistency if using multiple serums. Wait briefly between each for absorption.

Step 5: Eye Cream (Optional)

If you use a dedicated eye cream, apply it before moisturiser. The delicate eye area benefits from targeted treatment before heavier products are applied.

Step 6: Moisturiser

Apply your moisturiser to seal in all the previous products and provide hydration. Choose a lighter formula for morning—something that layers well under sunscreen and won't make your face feel greasy.

Step 7: Sunscreen

Sunscreen is always the last skincare step in your morning routine. Apply generously—about 1/4 teaspoon for your face—and give it a few minutes to set before applying makeup.

Morning Routine Quick Reference

  1. Cleanser
  2. Toner (optional)
  3. Vitamin C serum
  4. Additional serums (thinnest to thickest)
  5. Eye cream (optional)
  6. Moisturiser
  7. Sunscreen (always last)

The Complete Layering Order: Evening Routine

Evening routines are typically more extensive since you can use ingredients that aren't suitable for daytime (like retinoids) and don't need to worry about layering under makeup or sunscreen.

Step 1: Oil Cleanser or Micellar Water (First Cleanse)

If you wear sunscreen, makeup, or both, start with an oil-based cleanser or micellar water to dissolve these products. This is the "first cleanse" of a double-cleanse routine.

Step 2: Water-Based Cleanser (Second Cleanse)

Follow with your regular water-based cleanser to remove any remaining residue and cleanse the skin itself. This ensures products can penetrate effectively.

Step 3: Exfoliant (2-3 Times Weekly)

On exfoliation nights, apply your AHA, BHA, or gentle exfoliant after cleansing. Follow product instructions for timing—some need to be rinsed off, others are leave-on. Note: Don't use exfoliants on the same nights as retinoids when first building your routine.

Step 4: Toner or Essence

Apply hydrating or treatment toner to prep skin for subsequent products.

Step 5: Retinoid (On Non-Exfoliation Nights)

If using retinol or prescription retinoids, apply to clean, dry skin. Wait 20-30 minutes after cleansing to reduce irritation, especially when first starting retinoids. Use a pea-sized amount for your entire face.

Step 6: Treatment Serums

Apply any additional serums—hydrating serums, peptide serums, etc. Layer from thinnest to thickest.

Step 7: Eye Cream

Apply your evening eye treatment.

Step 8: Moisturiser or Night Cream

Finish with a nourishing moisturiser to seal everything in. Evening moisturisers can be richer than daytime formulas.

Step 9: Face Oil (Optional)

If you use a face oil, it goes last. Oils create an occlusive barrier, so any water-based products applied after will sit on top rather than absorbing.

Key Takeaway

Face oils always go last in your routine. They're occlusive and prevent water-based products from penetrating. The exception: mixing a drop of oil into your moisturiser is fine.

Common Layering Mistakes

Mistake 1: Not Waiting Between Products

Applying products too quickly in succession can cause pilling (that annoying thing where products ball up on your skin) and prevent proper absorption. Wait at least 30 seconds to 1 minute between products—longer for active serums like Vitamin C or retinoids.

Mistake 2: Applying Sunscreen Before Other Products

Sunscreen must be the last step before makeup. Applying anything on top of sunscreen can disturb the protective film and reduce effectiveness. Let your sunscreen set for 2-3 minutes before applying makeup.

Mistake 3: Using Oil-Based Products Before Water-Based

Facial oils and oil-based serums should always come after water-based products. If you apply oil first, your hydrating serums and water-based treatments can't penetrate through the lipid layer.

Mistake 4: Layering Incompatible Actives

Certain ingredients don't work well together:

  • Vitamin C + Retinol: Use at different times of day (Vitamin C morning, retinol evening)
  • AHAs/BHAs + Retinoids: Don't use simultaneously until your skin is well-adjusted to each
  • Benzoyl Peroxide + Vitamin C: Benzoyl peroxide oxidises Vitamin C
  • Multiple Strong Acids: Layering multiple acidic products can damage skin barrier

Mistake 5: Applying Products to Dry Skin

Many products—particularly hydrating serums and toners—work better on slightly damp skin. The moisture helps products spread evenly and can improve absorption of hydrating ingredients like hyaluronic acid.

How Long to Wait Between Products

Waiting times don't need to be excessive, but some patience helps products work better:

  • After cleansing: 30-60 seconds (skin should be slightly damp, not dripping)
  • After Vitamin C serum: 1-2 minutes (allows acidic pH to work)
  • After retinoid: 1-2 minutes (some prefer waiting up to 20 minutes before applying other products)
  • After other serums: 30-60 seconds (until absorbed)
  • After moisturiser: 1-2 minutes before sunscreen
  • After sunscreen: 2-3 minutes before makeup

When Less Is More

You don't need to use every product every day. A complicated routine can overwhelm skin and lead to irritation, breakouts, or sensitisation. Start with the basics—cleanser, one or two treatments, moisturiser, and sunscreen—and add products gradually.

Listen to your skin. If you're experiencing irritation, redness, or increased sensitivity, you may be using too many actives or layering products that don't work well together. Simplify and reintroduce products one at a time.

Sample Layering Routines

Simple Morning Routine (5 minutes)

  1. Gentle cleanser
  2. Vitamin C serum
  3. Moisturiser
  4. SPF 50+ sunscreen

Simple Evening Routine (5-10 minutes)

  1. Oil cleanser (if wearing sunscreen/makeup)
  2. Gentle cleanser
  3. Retinol serum (3-4 nights per week)
  4. Moisturiser

Conclusion

Mastering skincare layering isn't complicated once you understand the basic principles: thinnest to thickest, water-based before oil-based, and sunscreen always last. Give products time to absorb, avoid incompatible combinations, and don't overcomplicate your routine.

The best skincare routine is one you'll actually follow. If elaborate layering feels overwhelming, stick to the essentials—cleanser, Vitamin C, moisturiser, and sunscreen—and build from there as you become comfortable.

ET

Written by Emma Thompson

Emma spent five years working in cosmetic product development, bringing expertise in formulation and ingredient interactions to the Vitamin C Serum Australia team.